(B)WET TESTS FOR BASIC
RADICALS
Group
|
Group reagent
|
Cation
|
Precipitated( color)
|
|
I
|
Dil
HCL
|
Ag22+,Pb2+,Hg22+
|
Chloride(@white)
|
|
IIA
|
Dil HCL+H2S
|
Hg2+,Pb2+,Bi3+,Cu2+,Cd2+
|
Sulphide(@black)
|
black
|
IIB
|
Dil HCL+H2S
|
As3+,Sb3+,Sn2+/Sn4+
|
Sulphide(yellow,
|
yellow
|
Sb2S3@orange)
|
orange |
|||
IIIA
|
NH4Cl+NH4OH
|
Al3+,Cr3+,Fe3+
|
Hydroxides
|
|
Al(OH)3@white,
|
|
|||
Cr(OH)3@green,
|
green
|
|||
Fe(OH)3@brown
|
brown
|
|||
IIIB
|
NH4Cl+NH4OH+H2S
|
Co2+,Ni2+,Mn2+,Zn2+
|
Sulphide
|
|
CoS
|
Black
|
|||
NiS
|
Black
|
|||
MnS
|
Flesh
|
|||
ZnS(white)
|
|
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IV
|
NH4Cl+NH4OH+(NH4)2CO3
|
Ba2+,Sr2+,Ca2+
|
Carbonate(@white)
|
|
V
|
No particular group reagent
|
Na+,K+,NH4+,Mg2+
|
|
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